@ARTICLE{, 

TITLE={The electron-poor vinylcyclopropanes in organometallic catalysis: interesting skeletons with various reactivities}, 
  
AUTHOR={Maxime Laugeois, Maxime Vitale, Véronique Michelet, Virginie Ratovelomanana-Vidal, }, 
	
JOURNAL={Catalysis by Transition Metals}, 
	
VOLUME={1}, 

NUMBER={Issue 1}, 
	
YEAR={2019}, 

URL={https://openscience.fr/The-electron-poor-vinylcyclopropanes-in-organometallic-catalysis-interesting}, 
	
DOI={}, 
	
ISSN={}, 
	
ABSTRACT={Vinylcyclopropanes are molecules with extremely rich reactivity and among these, the electron-deficient vinylcyclopropanes have a "donor-acceptor" type polarization which gives them a particular reactivity. This article presents on the one hand the main routes of synthesis of electron-deficient vinylcyclopropanes under stoichiometric and catalytic conditions. On the other hand, the reactivity of the vinylcyclopropanes is presented in the presence of homogeneous organometallic catalysts: the rearrangement processes, functionalization reactions via ring opening and catalytic (3 + 2) cycloaddition reactions.}}